Dreher, Wolfgang
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Dreher, Wolfgang
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Dreher, Wolfgang
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wdreher@uni-bremen.de
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Item-typ:Veröffentlichung, Distribution of water in ceramic green bodies during drying(Elsevier, 2019-04-30); ; ; ; In order to investigate drying mechanisms at different stages, the distribution of water within the ceramic green bodies at different scales has been examined. The experimental measurements, using a simple weighing technique and Magnetic Resonance Imaging (MRI), show that during the first stage of drying involving shrinkage the material is constituted of uniquely solid and water with no gradient in water content within the sample. Then, during the second stage of drying, significant differences of water content as a function of position appear. As a complement, at the grain scale, observations using environmental scanning electron microscopy were made giving useful information on the solid–liquid–gas interfaces in the near surface part of the green body. Finally, the gradients in the water distribution were exploited to make a simple estimate of the diffusion coefficient of water with its dependence on the moisture content.Wissenschaftlicher ArtikelBand:39Heft:10156 102 - Some of the metrics are blocked by yourconsent settings
Item-typ:Veröffentlichung, Experimental Investigation of Local Hydrodynamics and Chemical Reactions in Taylor Flows Using Magnetic Resonance ImagingIn today's industrial processes reactions in dispersed gas–liquid systems are of major importance. Many products originate from gas–liquid reactions inside the bubble wake, acting as a mixing zone. High reaction yields are mainly influenced by the hydrodynamics within these zones. However, undisturbed hydrodynamic measurements of low viscous systems inside the bubble wakes are lacking. In this work we report on non-invasive MRI of gas–liquid Taylor flows. A detailed explanation of the developed MRI setup and sequence is given.Wissenschaftlicher Artikel27 32 - Some of the metrics are blocked by yourconsent settings
Item-typ:Veröffentlichung, Adapted MR velocimetry of slow liquid flow in porous media(Elsevier, 2017-02-04); ; ; ; MR velocimetry of liquid flow in opaque porous filters may play an important role in better understanding the mechanisms of deep bed filtration. With this knowledge, the efficiency of separating the suspended solid particles from the vertically flowing liquid can be improved, and thus a wide range of industrial applications such as wastewater treatment and desalination can be optimized. However, MR velocimetry is challenging for such studies due to the low velocities, the severe B0 inhomogeneity in porous structures, and the demand for high spatial resolution and an appropriate total measurement time during which the particle deposition will change velocities only marginally. In this work, a modified RARE-based MR velocimetry method is proposed to address these issues for velocity mapping on a deep bed filtration cell. A dedicated RF coil with a high filling factor is constructed considering the limited space available for the vertical cell in a horizontal MR magnet. Several means are applied to optimize the phase contrast RARE MRI pulse sequence for accurately measuring the phase contrast in a long echo train, even in the case of a low B1 homogeneity. Two means are of particular importance. One uses data acquired with zero flow to correct the phase contrast offsets from gradient imperfections, and the other combines the phase contrast from signals of both odd and even echoes. Results obtained on a 7T preclinical MR scanner indicate that the low velocities in the heterogeneous system can be correctly quantified with high spatial resolution and an adequate total measurement time, enabling future studies on flow during the filtration process.Wissenschaftlicher ArtikelBand:276126 130 - Some of the metrics are blocked by yourconsent settings
Item-typ:Veröffentlichung, Diffusion weighted magnetic resonance imaging for temperature measurements in catalyst supports with an axial gas flow(Royal Society of Chemistry, 2019-07-24); ; ; In situ thermometry of catalytic gas phase reactions allows the determination of temperature profiles in catalyst beds. In NMR imaging systems used for measuring the chemical composition of species in model reactors, temperature measurements by NMR spectroscopy are technically challenging and confined to a rather low temperature range. In this study, an optimized NMR in situ technique is proposed, which will allow the determination of the temperature distribution in highly exothermic reactions on structured catalysts. Diffusion weighted magnetic resonance imaging (DW-MRI) was successfully applied as an alternative method for temperature measurements commonly performed by chemical shift measurements using ethylene glycol. DW-MRI applied with different diffusion sensitizing gradients allows high-resolution imaging of the temperature dependent diffusion coefficient, without the need for high spatial homogeneity of the magnetic field. Using 3D DW-MRI on ethylene glycol, glycerol, and the temperature stable ionic liquid Pyr13 [TFSI] (decomposition temperature of 400 °C) as NMR thermometers, measurements were performed in a temperature range from 20 to 160 °C. The proposed method can be used in reaction engineering approaches performed in NMR systems.Wissenschaftlicher ArtikelBand:4109 137 - Some of the metrics are blocked by yourconsent settings
Item-typ:Veröffentlichung, NMR imaging of gas phase hydrogenation in a packed bed flow reactorIn situ analysis of heterogeneously catalyzed gas phase reaction systems is becoming a valuable aid to their modeling and optimization. The commonly applied methods are either invasive, do not provide spatial information or are not applicable for optically inaccessible systems. This work investigates the possibility to use NMR imaging to study gas phase reaction processes in situ, spatially resolved and non-invasively. A multislice NMR spectroscopic imaging pulse sequence, which was optimized to realize ultrashort echo time TE, was employed to study the ethylene hydrogenation reaction in an NMR-compatible packed bed flow reactor. The catalyst bed, containing inactive γ-Al2O3 pellets and Pt-Al2O3 pellets, was subdivided into several sections in order to identify reaction zones that depend on initial conditions. Spatial mapping of the chemical composition was demonstrated on the basis of two experiments with varying initial volume flow and ethylene conversion. The inlet and outlet temperature of the catalyst bed was simultaneously detected by analyzing the spectra of inserted glycol capsules. The resulting spatial shift of the reactive zones in both experiments could be proven by the spatially resolved concentration measurements and the temperature measurements. The locations of single active catalyst pellets were also detectable by the same measure. The quantitative results of product gas composition of both experiments were in good agreement with accompanying mass spectrometric measurements. The results demonstrate the applicability of NMR imaging methods to investigate gas phase reaction processes and can help to establish these methods as a standard tool to map chemical transformations in gas flow reactors.Wissenschaftlicher ArtikelBand:502142 149 - Some of the metrics are blocked by yourconsent settings
Item-typ:Veröffentlichung, In situ analysis of gas phase reaction processes within monolithic catalyst supports by applying NMR imaging methods(Elsevier, 2016-06-07); ; ; ; Measuring spatially resolved concentration distributions in gas phase reaction systems is an important tool to validate simulation calculations, improve the understanding of transport processes within the catalyst, and identify potentials for improvements of monolithic catalyst supports. The commonly used measurement methods for such opaque systems are invasive and, thus, might be misleading due to alteration of the system. To overcome this issue, a 3D magnetic resonance spectroscopic imaging (MRSI) method was developed and implemented on a 7-Tesla NMR imaging system to map the concentration distributions within opaque monolithic catalysts using the ethylene hydrogenation process as case study. The reaction was catalyzed by a coated sponge packing or a honeycomb monolith within an NMR compatible packed bed reactor. Temperatures at the inlet and the outlet of the catalyst beds were simultaneously determined by analyzing the spectra of inserted ethylene glycol filled glass capsules. Steady state concentration profiles and temperature levels were measured at different reaction conditions. In order to prove the plausibility of the measured spatial distributions of compound concentrations, the experimental results were compared to a 1D model of the reactor based on kinetic data from literature. Furthermore, a comparison with integral concentration measurements using a mass spectrometer demonstrated deviations below 5%. The results show that 3D MRSI is a valuable and reliable tool to non-invasively measure spatially resolved process parameters within optically and/or mechanically inaccessible structured monolithic catalyst supports, even if only standard thermal polarization is exploited and the use of expensive and technically challenging signal enhancement techniques (hyperpolarization) is avoided. We expect that 3D MRSI can pave the way toward deeper insight into the interactions between catalyst, catalyst support, and gas phase.Wissenschaftlicher ArtikelBand:273117 129 - Some of the metrics are blocked by yourconsent settings
Item-typ:Veröffentlichung, On the suppression of background signals originating from NMR hardware components. Application to zero echo time imaging and relaxation time analysisModern NMR imaging systems used for biomedical research are equipped with B0 gradient systems with strong maximum gradient strength and short switching time enabling (1)H NMR measurements of samples with very short transverse relaxation times. However, background signal originating from non-optimized RF coils may hamper experiments with ultrashort delays between RF excitation and signal reception. We demonstrate that two simple means, outer volume suppression and the use of shaped B0 fields produced by higher-order shim coils, allow a considerable suppression of disturbing background signals. Thus, the quality of NMR images acquired at ultrashort or zero echo time is improved and systematic errors in quantitative data evaluation are avoided. Fields of application comprise MRI with ultrashort echo time or relaxation time analysis, for both biomedical research and characterizing porous media filled with liquids or gases.Wissenschaftlicher Artikel114 95 - Some of the metrics are blocked by yourconsent settings
Item-typ:Veröffentlichung, Pore-scale analysis of axial and radial dispersion coefficients of gas flow in macroporous foam monoliths using NMR-based displacement measurements(Elsevier, 2020-02-06); ; ; ; A micro-scale analysis of mass transport in ceramic foams that are used as catalyst supports in gas phase reactions is of high interest. Although the effects of flow rate and foam parameters on the radial and axial dispersion are known for liquid flows, no pore-scale experimental analysis has been yet reported to correlate the mechanical and diffusional dispersion of gas flows to the geometry of open-cell foams. Here, a spatially resolved Pulsed Field Gradient NMR method is applied to determine dispersion coefficients of thermally polarized gas along axial and transversal directions of open-cell foams. The comparative study of three commercial foam samples with different morphologies shows the effect of open porosity, window size, and flow rate on gas dispersion. Additionally, the influence of mechanical and diffusional dispersion at each flow rate is investigated for individual samples. By observing the transition from diffusional dispersion to mechanically driven dispersion of gas, it is found that diffusional dispersion plays an important role, even at higher flow rates after a transition from Darcy to Darcy-Forchheimer regime occurs. The measured values for dispersion coefficients of methane can be directly used in pseudo-heterogeneous models for the methanation reaction.Wissenschaftlicher ArtikelBand:388132 98 - Some of the metrics are blocked by yourconsent settings
Item-typ:Veröffentlichung, Spatially Resolved Characterization of the Gas Propagator in Monolithic Structured Catalysts Using NMR DiffusiometryGas diffusivity measurements in opaque porous media were performed using nuclear magnetic resonance. An optimized pulsed-field gradient stimulated echo method with free volume selection was used to investigate the propagator of thermally polarized methane gas within commercial monolithic catalyst supports. Since signal losses due to T2 relaxation were minimized by using a short echo time, diffusion processes could be characterized by the measured propagator functions and effective diffusion coefficients were determined for a broad range of observation times and in different spatial directions. The study of this noninvasive characterization of gas diffusion found a clear effect of the monolith type and its pore size and coating on the effective gas diffusion coefficient and the apparent tortuosity for a given observation time.Wissenschaftlicher ArtikelBand:41Heft:9705 157 - Some of the metrics are blocked by yourconsent settings
Item-typ:Veröffentlichung, Colloid deposition in monolithic porous media – Experimental investigations using X-ray computed microtomography and magnetic resonance velocimetry(Elsevier, 2017-11-14); ; ; ; For experimental investigations of colloid retention in porous media, also denoted as deep bed filtration, X-ray computed microtomography (µCT) has become a basic tool within the last decade. On the one hand, µCT can spatially resolve particle deposition at discrete points of filtration time. On the other hand, the topological information of the porous media including the porosity and the pore size distribution can be obtained. Aside from structural parameters, the velocity field of the fluid within the pores, which cannot be measured by means of µCT, plays an important role in the underlying mechanisms of particle transport and immobilization. In a given structure, a high flow rate will result in increased velocity gradients as well as increased shear forces compared to a lower flow rate. High shear forces are in turn unfavorable for particle deposition. Another imaging modality, magnetic resonance velocimetry (MRV), is capable of quantifying the desired velocity maps. We demonstrate an experimental approach that combines both, MRV and µCT. In contrast to the majority of other investigations about colloid retention, the porous media investigated in this work are monolithic foam-like structures. The evaluation of colloid deposition in those monolithic filters is based on analyzing individual pores. Particle deposition in a pore is expressed by the volumetric fraction of particles while the pore flow is described by the Reynolds number. Results indicate that pores with high Reynolds numbers are not among the pores with the highest or lowest volume fraction of particles for a given time. The particle volume fraction in pores with low Reynolds numbers is mainly a function of the axial position of the pore.Wissenschaftlicher ArtikelBand:175116 125