Logo des Repositoriums
Zur Startseite
  • English
  • Deutsch
Anmelden
  1. Startseite
  2. SuUB
  3. Dissertationen
  4. Katalytische Eigenschaften ligandenmodifizierter, mono- und bimetallischer Nanopartikel.
 
Zitierlink URN
https://nbn-resolving.de/urn:nbn:de:gbv:46-00103703-11

Katalytische Eigenschaften ligandenmodifizierter, mono- und bimetallischer Nanopartikel.

Veröffentlichungsdatum
2014-03-07
Autoren
Altmann, Lena  
Betreuer
Bäumer, Marcus  
Gutachter
Arenz, Matthias  
Zusammenfassung
In this work, monometallic (Pt, Pd) and bimetallic (PtSn, CoPd) nanoparticles (NPs) of well-defined size and metal composition were prepared by colloidal synthesis methods. The mean particle diameter was about 2 nm for all samples irrespective of the metal composition or the presence of organic ligands during synthesis. This enables to systematically study the influence of the metal composition and a surface functionalization with organic ligands on the catalytic properties while excluding particle size effects. The catalytic properties of the monometallic and bimetallic nanoparticles were investigated in the hydrogenation of crotonaldehyde as well as the selective hydrogenation of acetylene to ethylene in ethylene-rich streams. Further, The influence of organic ligands on the geometric and electronic surface properties of colloidally prepared Pt nanoparticles (Pt NPs) was investigated by means of diffuse reflectance infrared spectroscopy (DRIFTS) using CO as probe molecule.
Schlagwörter
Heterogeneous catalysis

; 

Selective hydrogenation

; 

Platinum-tin alloys

; 

Colloidal nanoparticles

; 

organic ligands

; 

DRIFTS

; 

12CO/13CO Isotope Mixing Experiments
Institution
Universität Bremen  
Fachbereich
Fachbereich 02: Biologie/Chemie (FB 02)  
Dokumenttyp
Dissertation
Zweitveröffentlichung
Nein
Sprache
Deutsch
Dateien
Lade...
Vorschaubild
Name

00103703-1.pdf

Size

6.38 MB

Format

Adobe PDF

Checksum

(MD5):d65f885ab8b87fc08b44103401b9da62

Built with DSpace-CRIS software - Extension maintained and optimized by 4Science

  • Datenschutzbestimmungen
  • Endnutzervereinbarung
  • Feedback schicken