Synthesis of a chlorin with annelated lactam ring as subunit for artificial photosynthetic reaction centres
| File | Description | Size | Format | |
|---|---|---|---|---|
| 00106490-1.pdf | 584.07 kB | Adobe PDF | View/Open |
| Authors: | Montforts, Franz-Peter  Haake, Elmar |
| Other participants: | Haake, Elmar |
| Publisher: | Universität Bremen |
| Abstract: | A chlorin with an annelated cyclic ketone moiety was synthesized from a tricyclic nickel complex and appropriate pyrrole building blocks. Ketone functionality of the target chlorin allows Beckmann rearrangement to yield chlorin lactams. Lactam moieties on the chlorin represent masked amino acid structures which should allow formation of peptide-like backbones, along which chlorin pigments are arranged. Due to the natural chlorin chromophores and the peptide backbone the devices should represent artificial mimetics of natural photosynthesis systems. |
| Keywords: | Chlorin, pyrrole, Beckmann rearrangement, lactam, artificial photosynthesis |
| Issue Date: | 2018 |
| Journal/Edited collection: | Arkivoc Journal |
| Start page: | 102 |
| End page: | 113 |
| Type: | Artikel/Aufsatz |
| ISSN: | 1551-7012 |
| Secondary publication: | no |
| URN: | urn:nbn:de:gbv:46-00106490-17 |
| Institution: | Universität Bremen |
| Faculty: | Fachbereich 02: Biologie/Chemie (FB 02) |
| Institute: | Institut für Organische und Analytische Chemie |
| Appears in Collections: | Forschungsdokumente |
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