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  4. Synthese neuer Ringbausteine für Chlorophyll a und andere Chlorine aus Hagemanns-Ester
 
Zitierlink URN
https://nbn-resolving.de/urn:nbn:de:gbv:46-diss000105607

Synthese neuer Ringbausteine für Chlorophyll a und andere Chlorine aus Hagemanns-Ester

Veröffentlichungsdatum
2006-12-05
Autoren
dos Santos Filho, Jose Mauricio  
Betreuer
Montforts, Franz-Peter  
Gutachter
Stohrer, Wolf-Dieter  
Zusammenfassung
Total synthesis of naturally occurring products has been the most fecund field for developing new methodologies in Organic Chemistry. Interest in synthesis of chlorins has lead into investigation of new methodologies towards these natural products, including studies directed to total synthesis of chlorophyll a. With this objective we have developed a flexible synthetic concept for the synthesis of chlorins, which is based on the connection of four heterocyclic rings, leading to chlorin macrotetracycles. This work focused on the synthesis of new ring D building blocks from Hagemann's ester, which is an ease accessible starting material. Constitutional and sterochemical requirements have imposed the application of regio- and enantioselective protocols for obtaining appropriate intermediates to be transformed into the desired ring D units. The scope of enantioselective reductions of ketones as well as kinetic enzymatic resolution of alcohols derived from Hagemann's ester type was explored.
Schlagwörter
chlorins, chlrophyll a, Hagemann's ester, enantioselective synthesis.
Institution
Universität Bremen  
Fachbereich
Fachbereich 02: Biologie/Chemie (FB 02)  
Dokumenttyp
Dissertation
Zweitveröffentlichung
Nein
Sprache
Deutsch
Dateien
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Name

00010560.pdf

Size

2.29 MB

Format

Adobe PDF

Checksum

(MD5):ede6a27e1e7fa20bcab77c0552394a77

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