Röschenthaler, G.-V.Vlasov, KatjaKatjaVlasov2020-03-092020-03-092011-01-24https://media.suub.uni-bremen.de/handle/elib/168A range of new fluorine-containing lithium salts generating interest as novel electrolytes for lithium batteries were synthesized from 2,2-difluoro-2-fluorosulfonylacetyl fluoride in three steps. The novel lithium salts are non-sensitive to moisture, thermally and electrochemically stable. Furthermore, it was demonstrated that the Ruppert-Prakash reagent is able to react with a number of cyclic imines under acidic condition to afford the corresponding α trifluoromethyl derivatives of nitrogen heterocycles. 5-7 Membered cyclic imines bearing various alkyl, aryl or heterocyclic group were successfully involved in this transformation. Novel trifluoromethylated analogues of nicotine, anabasine and homoanabasine alkaloids were synthesized.deBitte wählen Sie eine Lizenz aus: (Unsere Empfehlung: CC-BY)fluorinated lithium saltsLithium-ion batteriesfluorinated phosphonatesRuppert-Prakash reagentnucleophilic trifluoromethylationcyclic iminestrifluoromethylated alkaloids540Dissertationurn:nbn:de:gbv:46-00102113-12