Syntheses, characterization, and coordination chemistry oforganoantimony(III) compounds with phenyl- and 2,6-dimesitylphenyl substituents

Breunig, Hans JoachimRat, Ciprian-Ionut2020-03-092020-03-092007-07-13https://media.suub.uni-bremen.de/handle/elib/2397The syntheses, spectroscopical and structural characterization by X-ray diffraction on single crystal of the series of complexes [W(CO)5(Ph2SbX)] (X = Cl, Br, I) and of organoantimony(III) compounds containing 2,6-dimesitylphenyl substituents are reported. The syntheses, spectroscopical data, and crystal structures of the first complexes of a stable distibene are discussed. Theoretical studies were carried out on the distibene complexes and on a series of catena stibines. The spectroscopical data of the first tristibine stable in the absence of a ring-chain equilibrium are reported.eninfo:eu-repo/semantics/openAccessantimonybismuthtungstentitaniumironDFTX-ray540Syntheses, characterization, and coordination chemistry oforganoantimony(III) compounds with phenyl- and 2,6-dimesitylphenyl substituentsSynthesen, Charakterisierung und Komplexchemie von Organoantimon(III)-Verbindungen mit Phenyl- und 2,6-Dimesitylphenyl SubstituentenDissertationurn:nbn:de:gbv:46-diss000107867