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  4. Crystal-chemical studies of cation-exchanged zeolite A
 
Zitierlink URN
https://nbn-resolving.de/urn:nbn:de:gbv:46-00105484-15

Crystal-chemical studies of cation-exchanged zeolite A

Veröffentlichungsdatum
2016-09-06
Autoren
Wang, Li  
Betreuer
Fischer, Reinhard X.  
Gutachter
Buhl, Josef-Christian  
Zusammenfassung
Powder and single crystals of K and NH4 exchanged zeolite A were prepared by static exchange methods. The crystal structure of hydrated zeolite K,Na-A and NH4-A were investigated by X-ray diffraction methods (space group Fm-3c) at ambient temperature. The refinement results indicated that all cations and large proportion of water molecules were located in the big grc units. The residual water molecules resided on the 6-fold axes in the toc units. In zeolite NH4-A, dealumination process occurred when the crystal stored in air. The thermal behavior of zeolite K-A, NH4-A and intermediate samples were studied by means of in situ X-ray powder diffraction combined with thermal gravimetric analyses in air and under vacuum conditions. Heavy atoms (Ba2 and Sr2 ) exchanged zeolite A were prepared. The results showed that the low X-ray intensity compared with zeolite Na-A was due to the high absorption coefficient of heavy atoms for X-rays.
Schlagwörter
dealumination

; 

thermal behavior

; 

single crystal
Institution
Universität Bremen  
Fachbereich
Fachbereich 05: Geowissenschaften (FB 05)  
Dokumenttyp
Dissertation
Zweitveröffentlichung
Nein
Sprache
Englisch
Dateien
Lade...
Vorschaubild
Name

00105484-1.pdf

Size

9.16 MB

Format

Adobe PDF

Checksum

(MD5):057b0cb831d2b12fb1aacb7c82236b16

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