Syntheses, characterization, and coordination chemistry oforganoantimony(III) compounds with phenyl- and 2,6-dimesitylphenyl substituents
Date Issued
2007-07-13
Author(s)
Supervisors
Abstract
The syntheses, spectroscopical and structural characterization by X-ray diffraction on single crystal of the series of complexes [W(CO)5(Ph2SbX)] (X = Cl, Br, I) and of organoantimony(III) compounds containing 2,6-dimesitylphenyl substituents are reported. The syntheses, spectroscopical data, and crystal structures of the first complexes of a stable distibene are discussed. Theoretical studies were carried out on the distibene complexes and on a series of catena stibines. The spectroscopical data of the first tristibine stable in the absence of a ring-chain equilibrium are reported.
Subjects
antimony
;
bismuth
;
tungsten
;
titanium
;
iron
;
DFT
;
X-ray
Institution
Type
Dissertation
Secondary publication
No
Language
English
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00010786.pdf
Size
3.53 MB
Format
Adobe PDF
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